Some Dobermans smile.
This is an unsettling thing to the unprepared owner. If you're not versed in the package of canine body language, such smiles might look like snarls. It is a lifting of the lip and a baring of the teeth. But there is no piloerection, no stiffness of posture; when I've seen it in pictures and video, it's been accompanied by body wiggles and airplane ears.
Of course, there are generally accepted "dog smiles" as well: